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Two people have been taken to a London hospital in a serious condition and a further two to a local hospital following a crash today.
Emergency crews - including firefighters and two air ambulance teams - were called to the A257 Canterbury Road following the collision shortly after midday.
A blue Ford Fiesta heading towards the city collided with a black Land Rover Discovery travelling in the opposite direction near Canterbury Golf Club.
Investigating officer Sergeant Chris Wade, from the Serious Collision Investigation Unit, said: "We would like to hear from anyone who witnessed the collision.
"If you can help, please phone the dedicated SCIU appeal line on 01622 798538, quoting 19-0365. Alternatively, email sciu.td@kent.pnn.police.uk."
The road remains shut between between the junctions of Bekesbourne Road, Littlebourne, and Stodmarsh Road, Canterbury.
Motorists heading out of the city are being diverted down Stodmarsh Road.
Listen to kmfm for travel updates.